What is silica gel and how does it work?
Silica gel is a solid desiccant (drying agent). It is not a wet gel as the name might suggest, and should not be confused with silicone gel. Silica gel is the most commonly used desiccant for providing efficient protection against excessive humidity in sealed spaces. This granular, vitreous, highly porous form of silica is made synthetically from sodium silicate. Silica gel beads contain millions of tiny pores that adsorb and hold water vapour and remain dry to the touch, even when fully saturated. This highly porous substance can adsorb up to 40 percent of its own weight at 50% RH and 25°C, and can take the relative humidity (RH) in a closed container down to about 40%, which makes this the highest water holding capacity, of any commercially used desiccant available. The adsorption up to 50% RH is a near‐linear relationship between the percentage of water uptake and the equilibrium relative humidity. This refined form of silica is produced in granular or beaded forms. Beaded silica gel has a higher mechanical strength than the granular form and is therefore less likely to generate dust. Also, the uniform bead size reduces gas flow channelling and minimises pressure drop. Silica gel is nearly harmless, which is why you find it in food products. Silica, or silicon dioxide (SiO2), is the same material found in quartz. Silica gel is essentially very porous sand. Some types of silica gel will "pop" when exposed to enough water. It can be reactivated and reused by heating.
Silica gel is produced synthetically by the reaction of a mineral acid, usually sulphuric, and a sodium silicate solution to form a gelatinous precipitate that is washed, and then dehydrated to produce colourless silica gel. Ammonium tetrachlorocobaltate(II) (NH4)2CoCl4 or cobalt chloride CoCl2 may be added to silica gel as a moisture indicator. These indicators change colour depending on hydration. Cobalt Chloride is blue when dehydrated and pink when saturated. Orange silica gel desiccant is the latest alternative to blue indicating silica gel (cobalt chloride). Orange silica gel is impregnated with a safe organic indicator that displays an orange/yellow colour when active and changes to green when the desiccant becomes saturated.

Silica Gel will continue to absorb moisture below freezing, but performs best at room temperatures.
Advantages
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Many manufacturers include silica gel packets in their electronics packaging which helps protect the electronics from moisture damage. Silica gel decreases moisture in the air which can limit the growth of mould and reduce spoilage. Silica gel may be used to dry electronic devices which had become wet. Placing the device in an airtight container with some silica gel, would remove most moisture, more effectively than air drying and more safely than heat. Storing electronic instruments in a sealed environment (plastic bag) with some silica gel prevents condensation and corrosion, which might cause serious damage.
Vitamins and pills are often packaged with silica gel packets to prevent damage or decomposition due to moisture in the bottle. If a bottle of vitamins contained any moisture vapour and was cooled rapidly, the condensing moisture would ruin the pills. Silica gel packets are also used to help keep dried food, like beef jerky and pepperoni, fresh. In museum and library exhibitions and storage, silica gel is used as a preservation tool to control relative humidity (RH) invaluable air tight frames. Leather goods are often transported with silica gels to help protect them from moisture damage. Storing leather goods with silica gel packets can also help protect them from moisture and make them last much longer.
If you have ever seen dried flowers and wondered how they managed to dry them and maintain the colours and shapes, they probably used silica gel. Covering the flowers with loose silica beads while they are still vibrant and firm dries them quickly, which helps maintain the colour and shape of the flowers. Silica gel can also be placed in a gun safe to help prevent moisture damage to both guns and ammunition.
Dry bags or dry boxes used in water sports, should contain silica gel to dry bags or dry boxes and absorb any moisture. Adding a silica gel packet to an underwater camera case absorbs moisture from within the case and limit or eliminates condensation from the camera's window.
Silica gel is most commonly encountered desiccant in everyday life, as clear beads packed in a semi‐permeable plastic. In this form, it is used as a desiccant to control local humidity to avoid spoilage or degradation of some goods. Because of poisonous doping agents (see below) and their very high adsorption of moisture, silica gel packets usually bear warnings for the user not to eat the contents. If consumed, pure silica gel is unlikely to cause acute or chronic illness, but if more than just a few beads are ingested the drying properties could cause some complications. Food‐grade desiccant should not include any poisons which would cause long‐term harm to humans if consumed in the quantities normally included with the items of food.
Silica in this form can be easily purchased for applications such as keeping tools rust free in damp environments, long term storage, and preservation of dried food. Silica gel can be used anywhere, but it is really only effective in an enclosed environment. In a situation where new air (and moisture) is frequently added, an impractical large amount of silica gel and frequent changes to dried silica gel would be required to keep relative humidity at low levels.
Applications:
See the list below for other areas where the silica gel dehumidifiers can be helpful in eliminating moisture. Depending on application, different volume or mixed silica gel may be packaged inside the following substrates; Tyvek, Non‐Woven, Plastic Film, Paper, Sewn Cloth, or Reinforced Paper.
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Note: Crystalline silica dust can cause silicosis but synthetic amorphous silica gel is non‐friable, and so does not cause silicosis.
In poorly sterilised situations, moisture may promote the growth of moulds, mildews and fungi. Products that use polymers are prone to swelling in high humidity conditions, due to water causing intermolecular bonds between polymer chains to weaken. If a very water soluble solid, such as sugar coating, is exhibited to the right conditions, dissolution can trigger irreversible water uptake and subsequent deliquescence.
Moisture in electronics causes corrosion and may lead to "short" circuits and other faults. Usually this will not produce sparks, the effects are more subtle, and the device may operate unreliably ‐ sometimes it work, sometimes it doesn't. A situation like this is frustrating, time‐wasting and may ruin an expensive instrument.
Silica gel adsorbs water up to 104°C, beyond that point it releases absorbed moisture. Bentonite clay adsorbs water only to 49°C at which point it begins to release any moisture back into the air. Both silica gel and bentonite clay can be reactivated for reuse. Bentonite clay and silica gel are used in industry, but silica gel is also commonly used in commerce and for domestic applications. Silica gel's absorbent capacity is 40% of its weight; bentonite clay's adsorbent capacity is only 25%. Silica gel's high adsorption capacity is the greatest available and considering its other desirable attributes (low dust, low toxicity and ability to absorb at higher temperatures) makes it the most popular desiccant.
The buffering capacity of silica gel is determined by measuring the moisture gained or lost by silica gel as the RH changes in the surrounding air. For museum applications, where the case will cycle within a controlled RH range, the buffering capacity of silica gel is measured by its moisture holding (MH) value, which takes into account changes in buffering capacity based on whether the RH increases or decreases.
Regular density silica gel is the most common type of silica gel and is universally available. RD silica gel is a form of silica manufactured from sodium silicate and sulphuric acid. Like clay, silica gel is non‐hazardous and is capable of adsorbing 40% of its weight in water vapour at 100% humidity. Because of its capacity for high moisture uptake in the low RH range, it is a very effective desiccant. For museum applications, the most important difference is buffering capacity, defined by the gel's MH value. Because of its poor hygroscopic properties around 45‐50% RH and above, it is not recommended for museum applications requiring control in the mid to upper RH range. Within the range of 40‐55% RH, it has an MH value of 2. Institutions located in areas with well defined wet and dry seasons, the buffering capacity of silica gel may become insufficient and the silica gel employed in sensitive cases may require replenishing. Recording a tray's silica gel net weight before and after drying will give a record of moisture levels. Silica gel has a porous molecular structure that closely resembles a sponge, and has the highest capacity of any commercial desiccant for moisture adsorption.
Molecular Sieve is a manufactured crystalline version of Zeolite containing a network of uniform pores and empty cavities. Molecular sieve is derived from sodium, potassium or calcium alumina silicate. It is a non‐hazardous material. Molecular sieve is the desiccant of choice for the most demanding applications; so it is used to remove traces of moisture from absolute ethanol or acetone. Molecular sieve is the most aggressive and expensive of the primary desiccants.
- Reactivating/ drying of silica gelSilica gel products can be dried and reused "as new". Orange silica gel: Dry pellets are orange and turn dark green when near saturation. Blue indicating silica gel: Dry it's dark blue and with increased water uptake it becomes more pale and pink. The most efficient method to reactivate silica gel is with heat. When heat is applied to saturated silica gel, the beads will restore to the previous moisture absorbing capability and return to the original orange colour. Unlimited regeneration cycles are possible.
Silica gel has a very high melting temperature, 1600°C. However, it will lose its chemically bound water and hygroscopic properties if heated above 300°C. In addition, there is a new class of indicator gels, incorporating organic dyes that are heat sensitive and their colour indicating dye will be affected above 125‐150°C . Therefore, it is not recommended that orange indicating silica gel is heated above 120°C. Also, if heated above 120°C through several reactivation cycles, the material may disintegrate into powder. This in turn, reduces the adsorption capacity of the material and may eventually lead to the loss of indicating colour within the crystals. The minimum heat necessary should be used when removing moisture from silica gel; ProSciTech recommends regeneration at between 105 °C and 120 °C. This will prevent the silica gel from deteriorating and it may be re‐generated numerous times.
Blue indicating silica gel has a higher tolerance and may be dried by heating it to 150°C. Lower heat for regeneration requires longer drying times, but the degradation of silica gel is reduced.
Increasing heat vapourises adsorbed moisture and above 105°C is removes all water molecule from silica gel. A porous desiccant like silica gel, removes water from the surrounding air by two mechanisms: multi‐layer adsorption and capillary condensation. Multi‐layer adsorption is the attraction of thin layers of water molecules to the surface of the desiccant. Since the desiccant is very porous, the surface area is high and significant amounts of water can be attracted and absorbed. Capillary condensation is when the smaller pores become filled with water. Capillary condensation occurs when saturated water vapour pressure in a small pore is reduced by the effect of surface tension.
In a conventional oven, the time of regeneration varies from minutes to hours, depending on temperature and the thickness of the gel within a dish. Although silica gel can be dried in a microwave oven, it is difficult to determine the temperature inside the gel. Particularly the orange gel should not be dried using microwaves since excessive heating denatures the indicator dye. As metal cannot be used in a microwave oven, only glass, ceramic or microwave safe plastic with a high melting temperature should be used to hold the gel.Place 'used' silica gel beads into a large tray
Use an oven at 105 ‐ 120°C for two hours, or continue heating for 30 minutes after the gel turned orange.
Check the silica gels beads periodically. Caution:the gel beads are very hot to touch.
Adsorption applies when one substance is being held inside another by physical bonds only. The term is used in surface chemistry and physics. So, a film of moisture is adsorbed onto cold surfaces. The surface is not chemically changed and when the surface is heated, the adsorbed water will mostly volatilise. Most desiccants do not absorb water or other substances. Instead, they capture molecules by adsorption and capillary action, they sequester them.
When silica gel is first placed into an enclosed area, it may be saturated quickly as it adsorbs residual moisture adsorbed on the specimens and chamber surfaces. After the residual dampness is removed, a dry condition can be maintained with less frequent need to reactivate the silica gel.
The more air tight the environment is, the less reactivation times needed. Making a chamber airtight will limit the amount of moisture leaking into the area. Also, avoid frequent opening of the desiccated space. For example, silica gel will work well within a storage trunk, but it will not work as well if the lid is opened and closed several times a day. The adsorption capacity of silica gel can be destroyed by contamination with dust, grease or petroleum products, and also by heating the material above 125°C.
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