Properties of Fused Quartz
Silica is found almost everywhere in nature, it represents almost 1/3 the mass of the earth's crust. Vitreous Silica is the generic term used to describe all types of silica glass, with manufacturers referring to the material as either Fused Quartz or Fused Silica.
Manufactured by fusing naturally occurring crystalline silica, either sand or rock crystal, a wide range of products are available that may be opaque, translucent or transparent. If the silicon dioxide is synthetically derived, the material produced is commonly called Synthetic Fused Silica.
Vitreous Silica, in all its forms, offers a variety of properties such as:
- Permeability
- Extreme Hardness
- Very Low Coefficient of Thermal Expansion
- Resistance to High Temperature
- High Chemical Purity
- High Corrosion Resistance
- Extensive Optical Transmission from Ultra-Violet to Infra-Red
- Excellent Electrical Insulation Qualities
- Remarkable Stability Under Atomic Bombardment
Properties
Density | 2.2 x 103 kg/m3 |
Hardness | 5.5-6.5 Mohs' Scale 570KHN100 |
Design Tensile Strength | 4.8 x 107 Pa (N/m²) |
Design Compressive Strength | Greater than 1.1 x 109 Pa |
Bulk Modulus | 3.7 x 1010 Pa |
Rigidity Modulus | 7.2 x 1010 Pa |
Young's Modulus | 7.2 x 1010 Pa |
Poisson's Ratio | 0.17 |
Coefficient of Thermal Expansion | 5.5 x 10-7 m/m
|
Thermal Conductivity (20°C) | 1.4 W/m
|
Specific Heat (20°) | 670 J/kg
|
Softening Point | 1956° |
Annealing Point | 1488° |
Strain Point | 1393° |
Electrical Resistivity | 7(107)ohm-m |
Dielectric Properties | (293°K and 1 MHz) |
Constant | 3.75 |
Strength | 5 x 107 V/m |
Loss Factor | Less than 4 x 10-4 |
Dissipation Factor | Less than 1 x 10-4 |
Index of Refraction | 1.4585 |
Constrigence (Nu value) Fused Quartz | 67.56 |
Velocity of Sound-Shear Wave | 3.75 x 103 m/s |
Velocity of Sound-Compression Wave | 5.90 x 103 m/s |
Sonic Attenuation | Less than 11 db/m
|
Permeability Constants | (cm
|
Helium | 210 x 10-10 |
Hydrogen | 21 x 10-10 |
Deuterium | 17 x 10-10 |
Neon | 905 x 10-10 |
TRACE IMPURITIES | ||||||||||
TYPE (PPM) | AI | AS | B | Ca | Cd | Cr | Cu | Fe | K | Li |
GE 124® | 14 | <.002 | <0.2 | 0.4 | <0.01 | <0.05 | <0.05 | 0.2 | 0.6 | 0.6 |
GE 214® | 14 | <.002 | <0.2 | 0.4 | <0.01 | 0.05 | <0.05 | 0.2 | 0.6 | 0.6 |
NSG OZ® | 40 | - | - | 2.5 | - | - | .50 | 0.9 | 1.7 | .06 |
TYPE (PPB) | Ag | Al | As | Au | B | Ba | Be | Bi | Ca | Cd |
Corning 7980 ® | <150 | -40 | <5 | n.d. | <100 | <14 | <5 | <10 | <20 | n.d. |
K | Li | Mg | Mn | Mo | Na | Ni | P | Sb | Sr | |
<21 | <1 | <25 | <10 | <5 | <150 | <7 | <100 | <5 | <3 |
TRACE IMPURITIES | |||||||||
TYPE (PPM) | Mg | Mn | Na | Ni | P | Sb | Ti | Zr | *OH- |
GE 124® | 0.1 | <0.05 | 0.7 | <0.1 | <0.2 | <0.003 | 1.1 | 0.8 | <5 |
GE 214® | 0.1 | <0.05 | 0.7 | <0.1 | <0.2 | <0.003 | 1.1 | 0.8 | <5 |
NSG OZ® | 0.3 | .03 | 2.5 | - | - | - | 0.8 | - | 200 |
TYPE (PPB) | Co | Cr | Cu | Fe | Ga | ||||
Corning 7980 ® | <10 | <1 | <13 | <15 | n.d. | ||||
Ti | U | V | Zn | Zr | |||||
<40 | <1 | <10 | <30 | <30 |
PRESSURE CALCULATIONS
INTERNAL PRESSURE CALCULATIONS RUPTURE FORMULA FOR TUBING Because fused quartz is used in applications involving internal pressures, it is helpful to know the maximum pressure that can be applied to a selected fused quartz tube. The formula at right can approximate this information at room temperature.
S = pr/t Where:S = Hoop Stress in Pa
p = Working Pressure (Pa)
r0 = Inside Radius (mm)
t = Wall Thickness (mm)
This formula can not be used when internal pressure exceeds 100 psi.
RUPTURE PRESSURE CALCULATIONS FOR DISCS AND PLATES
Determining pressure differential is required for many applications of stressed fused quartz discs, plates and sight glasses. The formulas below can be used for room temperature applications of parts having either clamped or unclamped edges.
A = Unsupported Area in sq/inches
T = Thickness (inches)
F = Safety Factor (7)
M = Modulus of Rupture (7,000 psi)
P = Pressure (psi)
THE ABOVE PRESSURE CALCULATIONS ARE RECOMMENDATIONS ONLY.
ACTUAL PRESSURE POINTS MAY VARY DEPENDING ON USER APPLICATIONS
FUSED QUARTZ PROPER USAGE GUIDELINES
Cleaning
The cleaning of fused quartz is critical before it is used in any application. The fused quartz should be cleaned by placing it in a 7% maximum solution of ammonium bifluoride for no more than ten (10) minutes, or a 10% volume maximum solution of hydrofloric acid for no more than five (5) minutes. After cleaning, using the above method, the fused quartz should be rinsed in deionised or distilled water and then dried.
Running in Procedure
In order to increase resistance to devitrification and sag of your quartzware, an even layer of cristobalite must be formed on the outer surface of quartz tubes. Expose a new tube to a temperature of up to 1200°C and rotate it 90° every two (2) hours for the first 12 to 24 hours.
Storage
Space permitting, fused quartz should be stored in its original shipping container. If that is not practical, at least the wrapping should be retained. In the case of tubing, the end coverings should be kept in place until the product is used. This protects the ends from chipping and keeps out dirt and moisture which could compromise the purity and performance of the tubing.
THESE PRODUCTS ARE ANNEALED
Both quartz and silica glass are annealed at approximately 1150°C. However, they reach a strain point at about 1120°C. These glass products, if rapidly cooled after use at temperatures above this strain point, will develop strain again. Special care should be taken when using large sized products.
JOINING FUSED QUARTZ AND OTHER MATERIALS
Quartz and silica glass only slightly expand with increases in temperature, in contrast with other materials. Care must be taken when these glass products are connected to other materials and the temperature rises, in order to avoid the development of cracks.
CARE MUST BE TAKEN DURING FURNACE INSERTION
Quartz and silica glass feature low thermal conductivity. If the glass product comes too close to a heating element, or is put in direct contact with a flame, it may become locally heated and develop cracks. Long glass tubes may also deform at temperatures of 1100°C or higher. Care should be taken to support both glass types, expecially large-sized products.
DEVITRIFICATION
Devitrification of quartz and silica glass means transition from a metastable (vitrified) state to a stable crystallised state of cristobalite. Devitrification occurs when the product is used at high temperatures over a long period of time, or it is heated while impurities adhere to its surface. Even very small impurities on the surface can have a major influence. Under such conditions, devitrification may even occur at temperatures of 1000°C or less. This hardly ever occurs at temperatures of 1150°C or less, if the glass surface is perfectly clean. Devitrification usually starts when the temperature rises to 1200°C or higher, then further develops as the temperature increases.
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